File:Chemical potentials vs log mole fraction.svg

Original file(SVG file, nominally 192 × 384 pixels, file size: 36 KB)

Commons-logo.svg This is a file from the Wikimedia Commons. The description on its description page there is shown below.
Commons is a freely licensed media file repository. You can help.

Summary

Description
English: Chemical potentials for various hypothetical non-ideal substances in solution. Since it is a log scale in mole fraction , the ideal appears as a straight line. For each case an ideal line has been drawn with its offset chosen to either align in the dilute () or the pure () limits.

The data shown are not for real substances but they do demonstrate realistic features. Their precise parameters were chosen more for graphical convenience.

In order top to bottom:

  • An ideal liquid component in an ideal mixture.
  • A non-ideal component that deviates positively (above pure-fixed ideal line), such as ethanol in water.
  • A non-ideal component that deviates negatively (below pure-fixed ideal line), such as acetone in chloroform.
  • A non-ideal solute such as sugar that has a saturation limit (maximum ). At this point the solute's chemical potential has risen above the chemical potential of the precipitate form (shown as a dot at ), therefore the solute preferentially exists as precipitate (i.e. phase separation would occur into saturated solution and precipitate).
  • A non-ideal electrolytic solute such as salt, that dissociates into ions. This is notable for the significant deviations from the ideal line even at low-ish concentrations, due to a contribution to the non-ideality ("ionic atmosphere effects" aka "salt effects"). This square root contribution makes it converge painfully slowly to the dilute limit, though it does so eventually. Also note that this is the average chemical potential per ion, e.g. for salt NaCl this would be the chemical potential , and the chemical potential of NaCl itself would be twice this (with twice the slope!).
The corresponding plot of activity coefficients is here: Activity coefficients vs log mole fraction.svg
Date
Source Own work
Author Nanite

Licensing

I, the copyright holder of this work, hereby publish it under the following license:
Creative Commons CC-Zero This file is made available under the Creative Commons CC0 1.0 Universal Public Domain Dedication.
The person who associated a work with this deed has dedicated the work to the public domain by waiving all of their rights to the work worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law. You can copy, modify, distribute and perform the work, even for commercial purposes, all without asking permission.

Captions

Chemical potentials for various hypothetical non-ideal substances in solution

Items portrayed in this file

depicts

16 March 2025

image/svg+xml

37,309 byte

cf6cf923edddafdfc511bce7eee0fc4ca55a730b

File history

Click on a date/time to view the file as it appeared at that time.

Date/TimeDimensionsUserComment
current13:46, 18 March 2025192 × 384 (36 KB)Nanitetweaks

The following page uses this file:

Metadata