VSEPR theory
The shape of a molecule or ion is determined by the repulsion between the electron pairs surrounding the central atom.
Valence Shell Electron-Pair Repulsion Theory
- Only the electron pairs arranged around the central atom in a covalent molecule need to be considered
- Pairs of electrons repel each other and move as far apart as possible
- Lone pair-lone pair repulsion is greater than lone pair-bonding pair repulsion which is greater than bonding pair- bonding pair repulsion
- The actual shape of species is determined by the atoms attached round the central atom (and influenced by the lone pairs of electrons)
- All bonds - single bonds, double bonds and triple bonds - take up the same space.
VSEPR Theory Media
Example of bent electron arrangement (water molecule). Shows location of unpaired electrons, bonded atoms, and bond angles. The bond angle for water is 104.5°.
- AX2E0-2D.svg
Linear molecule
Trigonal planar molecular geometry
Тетраэдрическая конфигурация молекул
- AX5E0-2D.svg
Trigonal bipyramidal molecular geometry
- AX4E1-2D.png
- AXED