Tetrasulfur tetranitride
Tetrasulfur tetranitride, also known as tetrasulphur tetranitride, is a chemical compound. Its chemical formula is S4N4. It contains sulfur in its +3 oxidation state. It also contains nitride ions.
Properties
It is a gold solid. It is an explosive, releasing sulfur and nitrogen when detonated. The purer the substance is, the more easily it explodes. It is pale yellow when cold, orange at normal temperature, and red when hot. It reacts with bases. It can be split into disulfur dinitride when it is reacted with silver. It does not dissolve in water.
Preparation
It can be made by reacting disulfur dichloride with ammonia. It can also be made by reacting ammonium chloride with disulfur dichloride.
Uses
It can be used to react with many organic compounds.
Safety
It is an explosive, so it should not be ground. Explosion releases harmless nitrogen and sulfur.
Tetrasulfur Tetranitride Media
Ball-and-stick model of the tetrasulfur tetranitride-boron trifluoride adduct, S4N4·BF3, from the crystal structure.*Single-crystal X-ray diffraction data and crystal structure from Inorg. Chem. (1967) 6, 1906–1910.*Model constructed in CrystalMaker 8.1. Image generated in
