Cobalt(II) fluoride

Cobalt(II) fluoride, also known as cobaltous fluoride, is a chemical compound. Its chemical formula is CoF2. It contains cobalt in its +2 oxidation state. It also contains fluoride ions.

Cobalt(II) fluoride
Fluorid kobaltnatý.PNG
Cobalt(II)-fluoride-unit-cell-3D-balls.png
IUPAC name Cobalt(II) fluoride
Other names cobalt difluoride
Identifiers
CAS number 10026-17-2
PubChem 24820
EC number 233-061-9
RTECS number GG0770000
SMILES F[Co]F
Properties
Molecular formula CoF2
Molar mass 96.93 g/mol
Appearance Red crystalline solid
Density 4.46 g/cm3 (anhydrous)
2.22 g/cm3 (tetrahydrate)
Melting point

1217 °C, 1490 K, 2223 °F

Boiling point
Solubility in water 1.4 g/100 mL (25 °C)
Solubility soluble in HF
insoluble in alcohol, ether, benzene
Structure
Crystal structure tetragonal (a,hydrous)
orthorhombic (tetrahydrate)
Hazards
NFPA 704

NFPA 704.svg

0
3
2
 
Related compounds
Other anions cobalt(II) oxide, cobalt(II) chloride
Other cations iron(II) fluoride, nickel(II) fluoride
Related compounds cobalt trifluoride
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Properties

It is a reddish crystalline solid. It only dissolves a little in water. The hydrate (type with water molecules attached) can dissolve in water. It can dissolve in acid. It can react with hydrogen at

Cobalt(II) Fluoride Media

300 °C (572 °F) to make cobalt and hydrogen fluoride.

Preparation

It can be made by reacting anhydrous (without any water molecules attached) cobalt(II) oxide or cobalt(II) chloride with a stream of hydrogen fluoride. This reaction makes the anhydrous form. The hydrated (with water molecules attached) form is made by reacting any cobalt(II) compound with hydrofluoric acid. When fluorine is reacted with cobalt at a high temperature, it makes both cobalt(II) fluoride and cobalt(III) fluoride.

Uses

It is used as a catalyst. It can be used as a source of the fluoride ion in dentist care. It is used in lenses.

Related pages